As director of the Methodist Episcopal Church's publishing concern, Peck was responsible for several historical biographies in what was then the new style of historiography, drawing on the use of original documents. These included a biography of John Wycliffe, and a history of the Wesley family.
He also published several tracts of his own work, most which were connected to the Holiness movement of the 1840s and 1850s.
- Christian exertion, or, The duty of private members of the Church of Christ to labor for the souls of men. s.n. 1845.
- National Evils and their Remedies: a discourse delivered on the occasion of the national fast, May 14, 1841 in the Methodist Episcopal Church, Greene-Street, New-York New York. G. Lane, 1841.
- Appeal from tradition and common sense, or an answer to the question, what constitutes the divine rule of faith and practice. New York. G. Lane, 1844.
- The Scripture doctrine of Christian perfection stated and defended: with practical illustrations and advices. In a series of lectures. Abridged from the author’s larger work. New York, Lane and Tippett, 1845.
- Slavery and the Episcopacy: being an examination of Dr. Bascom’s review of the reply of the majority to the protest of the minority of the late General conference of the M.E. Church, in the case of Bishop Andrew. New York, G. Lane & C.B. Tippett, 1845.
- Scripture doctrine of Christian perfection, with practical illustrations and advices in a series of lectures. New York, Lane & Scott, 1851.
- Lives of the apostles and evangelists. New-York, Pub. by Lane & Scott, for the Sunday-school union of the Methodist Episcopal church. 1851.
- The formation of manly character: a series of lectures to young men. New York, Carlton & Phillips, 1853.
- Wyoming (Pennsylvania) its history, stirring incidents and romantic adventures. New York, Harper & Brothers, 1858.
- Scripture doctrine of Christian perfection stated and defended: with a critical and historical examination of the controversy, ancient and modern. 1860.
- Early Methodism within the bounds of the old Genesee Conference. 1860.
- Our country, its trial and triumph, A series of discourses suggested by the varying events of the war for the union. New York, Carlton & Porter, 1865.
His
Sketches & incidents, or, A budget from the saddle-bags of a superannuated itinerant and
Life and Times of Reverend George Peck, DD, offered insight into the challenges facing the itinerant clergyman, or
circuit rider, as they had been called; by the time he published his memoirs in 1874, these roles for clergyman had long since disappeared.